| Date | BST/GMT | Home | Away | HT | Attend. | |||
|---|---|---|---|---|---|---|---|---|
| August 2012 | ||||||||
| Sun 26 | 19:45 | FT | Palermo | 0-3 | Napoli | 0-1 | 20,763 | Report |
| September 2012 | ||||||||
| Sun 2 | 19:45 | FT | Napoli | 2-1 | Fiorentina | 0-0 | 32,286 | Report |
| Sun 16 | 14:00 | FT | Napoli | 3-1 | Parma | 2-1 | 31,133 | Report |
| Sun 23 | 14:00 | FT | Catania | 0-0 | Napoli | 0-0 | 13,808 | Report |
| Wed 26 | 19:45 | FT | Napoli | 3-0 | Lazio | 2-0 | 34,433 | Report |
| Sun 30 | 14:00 | FT | Sampdoria | 0-1 | Napoli | 0-0 | 24,702 | Report |
| October 2012 | ||||||||
| Sun 7 | 19:45 | FT | Napoli | 2-1 | Udinese | 2-1 | 43,148 | Report |
| Sat 20 | 17:00 | FT | Juventus | 2-0 | Napoli | 0-0 | 40,562 | Report |
| Sun 28 | 19:45 | FT | Napoli | 1-0 | Chievo Verona | 0-0 | 34,953 | Report |
| Wed 31 | 19:45 | FT | Atalanta | 1-0 | Napoli | 1-0 | 14,883 | Report |
| November 2012 | ||||||||
| Sun 4 | 14:00 | FT | Napoli | 1-1 | Torino | 1-0 | 34,813 | Report |
| Sun 11 | 14:00 | FT | Genoa | 2-4 | Napoli | 1-0 | 20,581 | Report |
| Sat 17 | 19:45 | FT | Napoli | 2-2 | AC Milan | 2-1 | 52,546 | Report |
| Mon 26 | 18:00 | FT | Cagliari | 0-1 | Napoli | 0-0 | 15,000 | Report |
| December 2012 | ||||||||
| Sun 2 | 11:30 | FT | Napoli | 5-1 | US Pescara | 2-1 | 43,243 | Report |
| Sun 9 | 19:45 | FT | Internazionale | 2-1 | Napoli | 2-0 | 57,374 | Report |
| Sun 16 | 19:45 | FT | Napoli | 2-3 | Bologna | 0-1 | 26,023 | Report |
| Sat 22 | 14:00 | FT | Siena | 0-2 | Napoli | 0-0 | 9,489 | Report |
| January 2013 | ||||||||
| Sun 6 | 19:45 | FT | Napoli | 4-1 | AS Roma | 1-0 | 42,091 | Report |
| Sun 13 | 14:00 | FT | Napoli | 3-0 | Palermo | 2-0 | 27,777 | Report |
| Sun 20 | 11:30 | FT | Fiorentina | 1-1 | Napoli | 1-1 | 28,632 | Report |
| Sun 27 | 14:00 | FT | Parma | 1-2 | Napoli | 0-1 | 15,883 | Report |
| February 2013 | ||||||||
| Sat 2 | 19:45 | FT | Napoli | 2-0 | Catania | 2-0 | 46,055 | Report |
| Sat 9 | 19:45 | FT | Lazio | 1-1 | Napoli | 1-0 | 38,594 | Report |
| Sun 17 | 14:00 | FT | Napoli | 0-0 | Sampdoria | 0-0 | 41,734 | Report |
| Mon 25 | 18:00 | FT | Udinese | 0-0 | Napoli | 0-0 | 16,000 | Report |
| March 2013 | ||||||||
| Fri 1 | 19:45 | FT | Napoli | 1-1 | Juventus | 1-1 | 58,143 | Report |
| Sun 10 | 14:00 | FT | Chievo Verona | 2-0 | Napoli | 2-0 | 12,000 | Report |
| Sun 17 | 14:00 | FT | Napoli | 3-2 | Atalanta | 1-1 | 38,337 | Report |
| Sat 30 | 20:00 | FT | Torino | 3-5 | Napoli | 1-1 | 14,000 | Report |
| April 2013 | ||||||||
| Sun 7 | 19:45 | FT | Napoli | 2-0 | Genoa | 2-0 | 38,000 | Report |
| Sun 14 | 19:45 | FT | AC Milan | 1-1 | Napoli | 1-1 | 42,000 | Report |
| Sun 21 | 14:00 | FT | Napoli | 3-2 | Cagliari | 0-1 | 38,000 | Report |
| Sat 27 | 19:45 | FT | US Pescara | 0-3 | Napoli | 0-0 | 17,569 | Report |
| May 2013 | ||||||||
| Sun 5 | 19:45 | FT | Napoli | 3-1 | Internazionale | 2-1 | 39,000 | Report |
| Wed 8 | 19:45 | FT | Bologna | 0-3 | Napoli | 0-0 | 21,000 | Report |
| Sun 12 | 14:00 | FT | Napoli | 2-1 | Siena | 0-1 | 52,433 | Report |
| Sun 19 | 19:45 | FT | AS Roma | 2-1 | Napoli | 0-0 | 41,000 | Report |
