| Date | BST/GMT | Home | Away | HT | Attend. | |||
|---|---|---|---|---|---|---|---|---|
| August 2012 | ||||||||
| Sun 19 | 18:00 | FT | Real Madrid | 1-1 | Valencia | 1-1 | 78,000 | Report |
| Sun 26 | 22:00 | FT | Valencia | 3-3 | Deportivo La Coruña | 3-1 | 35,000 | Report |
| September 2012 | ||||||||
| Sun 2 | 20:30 | FT | Barcelona | 1-0 | Valencia | 1-0 | 76,352 | Report |
| Sat 15 | 17:00 | FT | Valencia | 2-1 | Celta Vigo | 1-1 | 37,000 | Report |
| Sun 23 | 11:00 | FT | Mallorca | 2-0 | Valencia | 1-0 | 14,495 | Report |
| Sat 29 | 15:00 | FT | Valencia | 2-0 | Real Zaragoza | 1-0 | 33,000 | Report |
| October 2012 | ||||||||
| Sun 7 | 11:00 | FT | Levante | 1-0 | Valencia | 1-0 | 20,060 | Report |
| Sat 20 | 19:00 | FT | Valencia | 3-2 | Athletic Bilbao | 1-2 | 36,000 | Report |
| Sat 27 | 17:00 | FT | Real Betis | 1-0 | Valencia | 1-0 | 33,000 | Report |
| November 2012 | ||||||||
| Sat 3 | 21:00 | FT | Valencia | 2-0 | Atlético Madrid | 1-0 | 53,000 | Report |
| Sun 11 | 11:00 | FT | Valladolid | 1-1 | Valencia | 0-1 | 15,512 | Report |
| Sat 17 | 17:00 | FT | Valencia | 2-1 | Espanyol | 1-1 | 38,000 | Report |
| Sat 24 | 19:00 | FT | Málaga | 4-0 | Valencia | 1-0 | 24,500 | Report |
| December 2012 | ||||||||
| Sat 1 | 17:00 | FT | Valencia | 2-5 | Real Sociedad | 1-1 | 38,000 | Report |
| Sat 8 | 21:00 | FT | Osasuna | 0-1 | Valencia | 0-0 | 15,849 | Report |
| Sun 16 | 16:00 | FT | Valencia | 0-1 | Rayo Vallecano | 0-0 | 35,000 | Report |
| Fri 21 | 19:00 | FT | Valencia | 4-2 | Getafe | 3-1 | 32,000 | Report |
| January 2013 | ||||||||
| Sat 5 | 17:00 | FT | Granada | 1-2 | Valencia | 0-0 | 21,000 | Report |
| Sat 12 | 21:00 | FT | Valencia | 2-0 | Sevilla FC | 0-0 | 30,000 | Report |
| Sun 20 | 20:00 | FT | Valencia | 0-5 | Real Madrid | 0-5 | 40,000 | Report |
| Sat 26 | 21:00 | FT | Deportivo La Coruña | 2-3 | Valencia | 2-1 | 33,000 | Report |
| February 2013 | ||||||||
| Sun 3 | 18:00 | FT | Valencia | 1-1 | Barcelona | 1-1 | 48,000 | Report |
| Sat 9 | 17:00 | FT | Celta Vigo | 0-1 | Valencia | 0-0 | 20,900 | Report |
| Sun 17 | 16:00 | FT | Valencia | 2-0 | Mallorca | 0-0 | 31,200 | Report |
| Sat 23 | 17:00 | FT | Real Zaragoza | 2-2 | Valencia | 2-1 | 19,000 | Report |
| March 2013 | ||||||||
| Sat 2 | 21:00 | FT | Valencia | 2-2 | Levante | 2-1 | 40,000 | Report |
| Sun 10 | 11:00 | FT | Athletic Bilbao | 1-0 | Valencia | 0-0 | 38,000 | Report |
| Sat 16 | 21:00 | FT | Valencia | 3-0 | Real Betis | 1-0 | 3,000 | Report |
| Sun 31 | 20:00 | FT | Atlético Madrid | 1-1 | Valencia | 1-1 | 49,000 | Report |
| April 2013 | ||||||||
| Sun 7 | 20:00 | FT | Valencia | 2-1 | Valladolid | 1-0 | 35,000 | Report |
| Sat 13 | 19:00 | FT | Espanyol | 3-3 | Valencia | 1-0 | 24,500 | Report |
| Sat 20 | 21:00 | FT | Valencia | 5-1 | Málaga | 4-1 | 41,000 | Report |
| Sun 28 | 20:00 | FT | Real Sociedad | 4-2 | Valencia | 1-1 | 28,097 | Report |
| May 2013 | ||||||||
| Sat 4 | 15:00 | FT | Valencia | 4-0 | Osasuna | 2-0 | 35,000 | Report |
| Sun 12 | 11:00 | FT | Rayo Vallecano | 0-4 | Valencia | 0-2 | 9,041 | Report |
| Sat 18 | 17:00 | FT | Getafe | 0-1 | Valencia | 0-1 | 9,000 | Report |
