Four-of-the-eight teams in the UCL quarterfinals are from the Premier League and the Nations League semis start four days after the decider.
Rice, 20, is still eligible switch to England having not made a competitive appearance for the Republic of Ireland.
Croatia defender Dejan Lovren has been banned for one international match over comments he made on social media about Spain and Sergio Ramos.
The UEFA Nations League failed to capture the imagination at first, but some stunning results have set up an intriguing final four.
Netherlands will face England in the semifinals of the UEFA Nations League.
England will take on Netherlands in Guimaraes on June 6, a day after Portugal play Switzerland in Porto.
The inaugural UEFA Nations League could be adversely affected by a decision to hold its first finals just days after the Champions League final.
A hat trick by in-form Scotland midfielder James Forrest earned them a 3-2 home win over Israel in Nations League promotion.
Sweden's Victor Lindelof and Marcus Berg secured a 2-0 win over Russia on Tuesday and promotion from Nations League B Group 2.
Poland forward Arkadiusz Milik scored from a twice-taken penalty to give his already-relegated side a 1-1 draw in Portugal.
Depending on your point of view, Koeman's switch was either the essence of Total Football or the age old tactic known as 'throw the big man up top.'
No team has had a worse 12 months in German national team history. So why was there so much positivity after Monday's 2-2 draw with the Netherlands?